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31.
《Advanced Powder Technology》2022,33(12):103847
We investigate synthesis, phase evolution, hollow and porous structure and magnetic properties of quasi-amorphous intermediate phase (QUAIPH) and hematite (α-Fe2O3) nanostructure synthesized by annealing of akaganeite (β-FeOOH) nanorods. It is found that the annealing temperature determines the phase composition of the products, the crystal structure/size dictates the magnetic properties whereas the final nanorod morphology is determined by the starting material. Annealing of β-FeOOH at ~300 °C resulted in the formation of hollow QUAIPH nanorods. The synthesized material shows low-cytotoxicity, superparamagnetism and good transverse relaxivity, which is rarely reported for QUAIPH. The QUAIPH nanorods started to transform to porous hematite nanostructures at ~350 °C and phase transformation was completed at 600 °C. During the annealing, the crystal structure changed from monoclinic (akaganeite) to quasi-amorphous and rhombohedral (hematite). Unusually, the crystallite size first decreased (akaganeite → QUAIPH) and then increased (QUAIPH → hematite) during annealing whereas the nanorods retained particle shape. The magnetic properties of the samples changed from antiferromagnetic (akaganeite) to superparamagnetic with blocking temperature TB = 84 K (QUAIPH) and finally to weak-ferromagnetic with the Morin transition at TM = 244 K and high coercivity HC = 1652 Oe (hematite). The low-cytotoxicity and MRI relaxivity (r2 = 5.80 mM?1 s?1 (akaganeite), r2 = 4.31 mM?1 s?1 (QUAIPH) and r2 = 5.17 mM?1 s?1 (hematite)) reveal potential for biomedical applications. 相似文献
32.
《Advanced Powder Technology》2022,33(12):103879
Heat transfer within ceramic feedstock powders is still unclear, which impedes optimization of the thermal and mechanical properties of the thermal sprayed coatings. The microspheres (yttria-stabilized zirconia YSZ and lanthanum zirconate LZO) were prepared via the electro-spraying assisted phase inversion method (ESP). The thermal properties of the two ESP microspheres and a commercial hollow spherical powder (HOSP) were investigated by using theoretical, experimental, and simulation methods. Thermal conductivity of the single microsphere was estimated via a novel nest model that was derived from the Maxwell-Eucken 1 and the EMT model. Thermal conductivity of a single YSZ/LZO-ESP microsphere prepared at 1100–1200 °C was within 0.36–0.75 W/m K, which was ~ 20 % lower than that of a single YSZ-HOSP microsphere with a similar porosity. Heat flux simulation showed that high tortuosity around the multi-scaled voids of the ESP microsphere led to a more efficient decrease in thermal conductivity compared with total porosity. 相似文献
33.
近年来,通过优化飞行程序降低机场飞机噪声影响成为机场环境保护的重要研究方向。文章首先建立了基于飞机“噪声-功率-距离”数据的噪声计算模型,介绍了平均飞行航迹以及连续爬升运行(Continuous Climb Opera-tion, CCO)离场程序的相关理论,最后以大型国际机场为实例,使用飞机平均飞行航迹进行噪声预测,运用综合噪声模型计算出噪声影响面积并绘制噪声影响等值线图,比较了CCO离场相对常规的标准仪表离场(Standard Instru-ment Departure, SID)的降噪效果。结果表明,CCO离场程序可有效降低机场噪声影响,在高噪声级影响区域的降噪效果更佳。 相似文献
34.
《International Journal of Hydrogen Energy》2022,47(32):14580-14588
Recovery of hydrogen (H2) from H2-containing gas mixtures has great significance for energy conservation, cost reduction and benefit increase. However, the common separation methods have the ubiquitous problem due to phase equilibrium principle and results in the conflict between H2 concentration and H2 recovery rate in the product gas. Consequently, an innovative conception of hydrate-membrane coupling approach is proposed in this work. In the separation process, hydration and membrane permeation two separation driving forces coexist to achieve the aim of strengthening mass transfer kinetics. H2 and non-H2 components (hydrocarbons) are synchronously and directionally selected by membrane and hydrate to improve different phase compositions. Therefore, the gas in feed side could keep relatively high two separation driving forces (H2 fugacity and hydrocarbons fugacity). The results show that the coupling method could synchronously increase both the concentration and the recovery rate of H2 in the product gas. At the same time, the volume and concentration of the hydrocarbons in hydrate both increases effectively. It indicates that hydrate and membrane separation methods support each other in the separation process. The hydrate-membrane coupling method fundamentally solves the issue of the decreasing driving force resulting from single separation method and phase equilibrium relationship. 相似文献
35.
《International Journal of Hydrogen Energy》2022,47(63):27080-27095
The study of shock wave propagation in a detonation chamber is of great importance as a part of the plate forming process. Investigations related to the effects of premixed gas detonation on the deflection of a plate require in-depth examination. An Eulerian-Lagrangian numerical simulation is conducted using the space-time conservation element and solution element method of LS-DYNA software to study the effect of confined multi-point ignited gaseous mixture on the dynamic response of thin plates clamped at the end of a combustion chamber. The FSI couples a Lagrangian finite element solver with a Eulerian fluid solver in a 2D space with detailed chemistry of H2–O2 mixture. The solution contains the detonation wave propagation through the combustion chamber and its interaction with the plate. The influence of variation in the multi-point ignition locations and combustion chamber dimensions on the pressure history and plate deflection is studied. To verify the model, a comparison with the experimental study is carried out using an adjustable model representative of the real experiment. The verified model is used to link the evolution of plate shape with the arrival time and intensity of shock waves within the chamber. It is found that a longer distance between the ignition point and the plate intensifies the ultimate deflection of the plate. In addition, a fairly large combustion area employed in a direction rather than transverse to the plate surface is unable to influence the ultimate deformation of the plate. 相似文献
36.
《International Journal of Hydrogen Energy》2022,47(67):28879-28893
A novel Z-type multidimensional FeSe2/CuSe heterojunction photocatalyst was synthesized by a hydrothermal progress. In the reaction, 1D FeSe2 nanorods will load on the surface of 2D CuSe nanosheets to construct heterojunction. This Z-type heterojunction can improve the carriers separated efficiency and reduce internal resistance (as low as 0.31 kΩ). More importantly, the catalysts display both high oxidation and reduction ability confirmed by photocatalytic and photoelectrochemical test. Under the optimum concentration, the catalyst showed 7.4 times of degradation tetracycline hydrochloride rate, and 4 times of photocurrent density than pure CuSe. Active specie O2?? was detected by the electron spin resonance tool during photocatalytic degradation progress which could confirm that a Z-type heterojunction was constructed between CuSe and FeSe2. In this Z-type heterojunction, photoinduced electrons in the conduction band of FeSe2 can directly inject the valence band of CuSe while photoinduced electrons in the conduction band position of CuSe and photoinduced holes in the valence band position of FeSe2 will remain. The remained photoinduced electrons in the conduction band of CuSe can generate O2?? to oxide tetracycline hydrochloride as well as photoinduced electrons to produce hydrogen. This work highlights a simple strategy of Z-tpye selenides heterostructure for oxidation and reduction application. 相似文献
37.
《International Journal of Hydrogen Energy》2022,47(93):39486-39498
Adjusting the band gap of organic-inorganic composites by chemical bonding can effectively construct Step-scheme (S-scheme) heterojunctions, featuring properties of fast photogenerated charge migration and excellent photocatalytic performance. In this work, a novel perylene-3, 4, 9, 10-tetracarboxylicdiimide (PDI)-titanium dioxide (TiO2) heterojunction is elaborately synthesized through simple solvent compounding method. The monodispersed spherical TiO2 nanoparticles was prepared with the capping agents of oleylamine and oleic acid, and suffered by a ligand exchange process with nitrosonium tetrafluoroborate (NOBF4) to remove oleylamine and oleic acid. The NOBF4 ligands were further replaced by PDI super molecular nanosheets to obtain two dimensional (2D)-zero dimensional (0D) PDI-TiO2 composites. TiO2 nanoparticles are evenly anchored on the surface of PDI nanosheets with intimate contact. The PDI-TiO2 composites has emerged considerably superior activity in hydrogen evolution. The highest hydrogen evolution rate for PDI-TiO2composites with the PDI weight percentage of 2.4% was 9766 μmol h?1 g?1 under solar light irradiation, which is 2.56 times of TiO2-NOBF4 catalyst. Moreover, PDI-TiO2 composites possess stoichiometric overall water splitting performance with H2 and O2 release rates of 238.20 and 114.18 μmol h?1 g?1. The superior photocatalytic performance of PDI-TiO2 composites can be attributed to the dramatic increase in visible and NIR light absorption caused by π-π stacking structure of PDI, the prevented charge recombination by the S-scheme heterojunction, and the enhanced oxygen evolution by the stronger oxidation capability of PDI. PDI supramolecular nanosheets may work as a novel functional support for many types of semiconductor nanomaterials as graphene, which will display a wide range of application prospects in the energy and environmental fields. 相似文献
38.
Xiuyun Guo Junjun Wu Xiangren Meng Yawei Zhang Zengqi Peng 《International Journal of Food Science & Technology》2022,57(4):2556-2567
This study investigated the effects of l -lysine (Lys) and l -histidine (His) on the oxidative characteristics and gel properties of porcine myofibrillar proteins (MP). Results showed that Lys and His had a strong ferrous ion-chelating ability and hydroxyl radical-scavenging activity. Moreover, Lys and His inhibited the protein carbonyl formation and MP aggregation at 0.2 M and 0.6 M NaCl, respectively, in a dose-dependent manner. Furthermore, 2 and 4 mg mL−1 Lys and His decreased the oxidation-induced loss of the tertiary structure of MP accompanied by the lower surface hydrophobicity. The water-holding capacity and gel strength of MP gels increased with increasing Lys and His concentrations due to more regular and lamellar structures with smaller and homogeneous pores at 0.6 M NaCl and more orderly crosslinking via fibrous filament at 0.2 M NaCl. In summary, Lys and His chelated the ferrous ions and scavenged hydroxyl radicals, decreased the oxidation-induced physicochemical changes, thus preventing oxidative damage during the formation of a three-dimensional gel network, which resulted in better gel quality. 相似文献
39.
Flow phenomena of three-dimensional conducting Casson fluid through a stretching sheet are proposed in the present investigation with the impact of the magnetic parameter in a permeable medium. The adaptation of particular transformations is useful to modify the governing equations into their nondimensional as well as the ordinary form. However, these transformed equations are nonlinear and approximate analytical methods for the solution of the complex form of governing equations. In particular, the Adomian decomposition method is proposed for the solution. The behavior of several variables, such as the magnetic and porous matrix, on the flow profile as well as the rate of shear stress, are discussed via graphs and tables. The conformity of the current result with the earlier study shows a road map for further investigation. The major concluding remarks are; the retardation in the velocity distribution is rendered due to an increase in the Casson parameter moreover, the Casson parameter favors in reducing the rate of shear stress coefficient in magnitude. 相似文献
40.
《Soils and Foundations》2022,62(3):101156
In this paper, a newly developed 3-dimentional discrete element model (DEM) for gravel-rubber mixtures (GRMs), namely DEM4GRM, that is capable of accurately describing the macro-scale shear response (from small to large deformation) of GRMs in a direct shear box apparatus is presented. Rigid gravel grains are modelled as simple multi-shape clumps, while soft rubber particles are modeled by using deformable 35-ball body-centered-cubic clusters. Mixtures are prepared with different volumetric rubber content (VRC) at 0, 10, 25, 40 and 100%, statically compressed under 30, 60 and 100 kPa vertical stress and then sheared, by closely simulating a reference laboratory test procedure. The variation of micro-scale factors such as fabric, normal and tangential force anisotropy is carefully examined throughout the shearing process and described by means of novel micro-mechanical relationships valid for GRMs. Moreover, strong-force chains are scrutinized to identify the transition from rigid to soft granular skeleton and gain insights on the load transfer and deformation mechanisms of GRMs. It is shown that the development of the fabric and force anisotropy during shearing is closely related to the macro-scale shear strength of GRMs, and strongly depends on the VRC. Besides, strong-force chains appear to be primarily formed by gravel-gravel contacts (resulting in a rigid-like mechanical behavior) up to VRC = 30%, and by rubber-rubber contacts (causing a soft-like mechanical response) beyond VRC = 60%. Alternatively, at 30% < VRC < 60%, gravel-rubber contacts are predominant in the strong-force network and an intermediate mechanical behavior is observed. This is consistent with the behavioral trends observed in the macro- and micro-mechanical responses. 相似文献